Introduction of polyketone resin
Polyketone resin (also called aldehyde ketone resin) is neutral, nontoxic hard resin coming from the polycondensate of aldehyde ketone. It is colorless of light yellow transparent granule or white powder with good solubility. As a multifunctional modified resin, it is soluble in all common solvents except for aliphatic hydrocarbon for coating industry.
Due to its molecular structure, polyketone resin has special quality and characters. The saturated cyclic structure formed during the polycondensation of resin leads to high luster, hardness, anti-degradation and weather- endurance. Such resin is good in water resistance because of the lack of ester bonds and in heat stability due to the cyclohexyl in principal bonds. In addition, the polarity of ketone groups and hydroxyl groups contributes to its extensive mutual solubility, good dye wettability and adhesion. So it is compatible with compounds of extreme great and extreme weak polarity. As the ideal raw material of the majority of printing ink, dye and adhesives systems, it is suitable to improve their rapid-drying property, luster, adhesion, leveling, dye wettability, weather endurance and solid contents.
Specifications of polyketone resin
Item | unit | index | Measurement method | |||
K90 | K100 | K110 | K120 | |||
Softening point | 85~95 | 95~105 | 105~115 | 115~125 | GB12007.6-1989 | |
color | Fe-Co | ≤1 | ≤1 | ≤1 | ≤1 | GB/T12007.1-1989 |
Acid value | mgKOH/g | 0 | 0 | 0 | 0 | GB1668-1995 |
Hydroxyl value | mgKOH/g | ~110 | ~110 | ~90 | ~90 | GB/T7581-1985 |
viscosity | ||||||
Molecule weight | ||||||
Solubility
Polyketone resin is soluble in all general solvents for coating industry except for water and aliphatic hydrocarbon, such as alcohol, ketone, ester, ether and blended solvents.
methyl butyl ketone | A | benzene | A |
cyclohexanone | A | ester | A |
ether | A | alcohol | A |
Water, petroleum ether | C | 200# solvent oil | C |
Note: A indicates it can be solved and diluted at any ratio; B indicates it can be solved and diluted at any ratio when the content is more than 30%; C indicates it cant be solved or diluted.
With blended solvent or heating, the solution rate of the resin will grow.
Polyketone resin has good compatibility with most resins and
plasticizers.
Base stock and plasticizers | Compati- bility | Base stock and plasticizers | Compati- bility |
epoxy resin | A | styrenated alkyd | A |
carbamide resin | A | maleic acid resin | A 2 |
rosin resin | A | saturated alkyd resin | A |
phenolic resin | A | hydrocarbon resin | C |
polyamide resin | A | styryl acrylic resin | A |
amino resin | A | vinyl resin | A |
maleic resin | A | short-oil alkyd | A |
acrylic resin | A-B | medium-oil alkyd | B |
chlorinated rubber | A | long-oil alkyd | C |
chlorparaffins | A | maleic acid anhydride resin | A |
chlorethene copolymers | A | nitryl cellulose | A |
benzene anhydride plasticizer | A | calcium sylvate | A |
alkyl sulfonic ester plasticizer | A | calcium resinate | B |
Note: A means compatibleB means limited compatible; C means incompatible.
The above results are obtained by measuring the mixture dried by air on the surface of glass.
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